Van der Waals's equation of state is obeyed by real gases. For $n$ moles of a real gas,the expression will be :-

  • A
    $\left( \frac{P}{n} + \frac{na}{V^2} \right) \left( \frac{V}{n - b} \right) = RT$
  • B
    $\left( P + \frac{a}{V^2} \right) (V - b) = nRT$
  • C
    $\left( P + \frac{na}{V^2} \right) (nV - b) = nRT$
  • D
    $\left( P + \frac{n^2 a}{V^2} \right) (V - nb) = nRT$

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What is the correction term in the pressure for real gas in comparison to the ideal gas?

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Assertion : Greater the value of van der Waal's constant $a$,greater is the liquefaction of gas.
Reason : $a$ indirectly measures the magnitude of attractive forces between the molecules.

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